rabbithong 2007-10-08 16:45
Surface-Enhanced Vibrational Spectroscopy
Surface-Enhanced Vibrational Spectroscopy
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[img]http://media.wiley.com/product_data/coverImage300/12/04716073/0471607312.jpg[/img]
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Ricardo Aroca 8B
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ISBN: 978-0-471-60731-1)mD/f^6z:@"Q*g5a
Hardcover
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260 pages)uR-A9OO.{!Y h
May 2006
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Wiley List Price: US $140.00
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Preface.
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Acknowledgments. 2VH$x"o}'`2]j[
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Glossary. ;~+t(YU?&k4G$AY.V
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1. Theory of Molecular Vibrations. The Origin of Infrared and Raman Spectra. /G3N0Qv P5p+H
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1.1 Electronic, Vibrational, Rotational and Translational Energy.
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1.2 Separation of Nuclear and Electronic Motions. t x-j;nWiu9Bm.T
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1.3 Vibrations in Polyatomic Molecules. &E {$g"aP5N-[w
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1.4 Equilibrium Properties. Dipole Moment and Polarizability.
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1.5 Fundamental Vibrational Transitions in the Infrared and Raman Regions.
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1.6 Symmetry of Normal Modes and Vibrational States.
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1.7 Selection Rules.
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1.8 The Example of ab initio Computation of the Raman and Infrared Spectra.
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1.9 Vibrational Intensities.
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1.10 Definition of Cross-Section.
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1.11 The Units of Energy and Force Constants. c%r~;D%Tr
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References.
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2. The Interaction of Light with Nanoscopic Metal Particles and Molecules on Smooth Reflecting Surfaces. J6X F6c$SR Yz
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2.1 Electric Permittivity and Refractive Index. w }\hS U q%D RO&}2w
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2.2 Propagation of Electromagnetic Waves and the Optical Properties of Materials.
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2.3 Scattering and Absorption by Nanoscopic Particles. -n&\}ol](Y
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2.4 Reflection–Absorption Infrared Spectroscopy on Smooth Metal Surfaces.
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References.
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3. Surface-Enhanced Raman Scattering (SERS). C`Z k$X`
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3.1 Electromagnetic Enhancement Mechanism. (q{r'z5Pc
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4. Chemical Effects and the SERS Spectrum. C+~!qv I
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4.1 Physical and Chemical Adsorption.
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4.2 SERS/SERRS of Physically Adsorbed Molecules.
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4.3 SERS of Chemically Adsorbed Molecules without Electronic Resonance Excitation.
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4.4 SERS of Chemically Adsorbed Molecules with Charge Transfer Excitation. -C y)x [r-e
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4.5 Metal–Molecule or Molecule–Metal Charge Transfer.
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4.6 SERRS from a Surface Complex.
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References.
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5. Is SERS Molecule Specific? 5yMTaV.I)y9q
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References.
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6. SERS/SERRS, the Analytical Tool.
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6.1 Average SERS on Metal Colloids. Preparation and Properties. 3VB$d b#x6nQ
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6.2 Metal Colloids. The Background SERS.
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6.3 Metal Colloids. Maximizing the Average SERS in Solution.
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6.4 Average SERS on Metal Island Films.
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6.5 Average SERS on Rough Electrodes.
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6.6 Ultrasensitive SERS Analysis and Single Molecule Detection. Syz8H4S
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6.7 Uniqueness of Ultrasensitive Chemical Analysis. The Moving Target.
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6.8 Applications and Outlook. 7~iMg G(jjL&K^m
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References.
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7. Surface-Enhanced Infrared Spectroscopy.
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7.1 Overview.
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7.2 Theoretical Models for SEIRA.
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7.3 SEIRA-Active Substrates.
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7.4 Interpretation of the Observed SEIRA Spectra.
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7.5 Applications of SEIRA. 4F#h1Vb)U U(oM
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Index.