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Advances in the controlled growth of nanoclusters using a dendritic architecture

Advances in the controlled growth of nanoclusters using a dendritic architecture
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)z:`4p2b4jx7fN Jason K. Vohs and Bradley D. Fahlman
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u!pf9Ap.t!d New J. Chem., 2007, 31, 1041 - 1051
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The dendritic architecture represents the fourth major class of polymers. Though hyperbranched polymers and structurally-perfect dendrimers (e.g., poly(amidoamine), PAMAM) both share this designation, the latter are of greater use for nanoreactor applications. One such application that exploits the container/reactor properties of dendrimers is the controlled growth of nanoclusters. Herein, we provide a review of the recent synthetic methods for nanocluster growth using a dendritic host, and their use in a variety of applications. The benefits of using this macromolecular host will also be discussed, within a historical context of colloidal entraining agents.
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